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Abstract Phosphorus is a key element that plays an essential role in biological processes important for living organisms on Earth. The origin and connection of phosphorus-bearing molecules to early solar system objects and star-forming molecular clouds is therefore of great interest, yet there are limited observations throughout different stages of low-mass (M < a few solar masses) star formation. Observations from the Yebes 40 m and IRAM 30 m telescopes detect for the first time in the 7 mm, 3 mm, and 2 mm bands multiple transitions of PN and PO, as well as a single transition of PO⁺, toward a low-mass starless core. The presence of PN, PO, and PO⁺is kinematically correlated with bright SiO(1–0) emission. Our results reveal not only that shocks are the main driver of releasing phosphorus from dust grains and into the gas phase but that the emission originates from gas not affiliated with the shock itself but quiescent gas that has been shocked in the recent past. From radiative transfer calculations, the PO/PN abundance ratio is found to be $3.1_{-0.6}^{+0.4}$, consistent with other high-mass and low-mass star-forming regions. This first detection of PO⁺toward any low-mass star-forming region reveals a PO⁺/PO ratio of $0.0115_{-0.0009}^{+0.0008}$, a factor of 10 lower than previously determined from observations of a Galactic center molecular cloud, suggesting its formation can occur under more standard Galactic cosmic-ray ionization rates. These results motivate the need for additional observations that can better disentangle the physical mechanisms and chemical drivers of this precursor of prebiotic chemistry. 

ABSTRACT Cold ($$\sim$$10 K) and dense ($$\sim 10^{5}$$ cm$$^{-3}$$) cores of gas and dust within molecular clouds, known as starless and dynamically evolved pre-stellar cores, are the birthplaces of low-mass (M$$\le$$ few M$$_\odot$$) stars. As detections of interstellar complex organic molecules, or COMs, in starless cores has increased, abundance comparisons suggest that some COMs might be seeded early in the star formation process and inherited to later stages (i.e. protostellar discs and eventually comets). To date observations of COMs in starless cores have been limited, with most detections reported solely in the Taurus molecular cloud. It is therefore still a question whether different environments affect abundances. We have surveyed 35 starless and pre-stellar cores in the Perseus molecular cloud with the Arizona Radio Observatory (ARO) 12 m telescope detecting both methanol, CH$$_3$$OH, and acetaldehyde, CH$$_3$$CHO, in 100 per cent and 49 per cent of the sample, respectively. In the sub-sample of 15 cores where CH$$_3$$CHO was detected at $$\gt 3\sigma$$ ($$\sim$$18 mK) with the ARO 12 m, follow-up observations with the Yebes 40 m telescope were carried out. Detections of formic acid, t-HCOOH, ketene, H$$_2$$CCO, methyl cyanide, CH$$_3$$CN, vinyl cyanide, CH$$_2$$CHCN, methyl formate, HCOOCH$$_3$$, and dimethyl ether, CH$$_3$$OCH$$_3$$, are seen in at least 20 per cent of the cores. We discuss detection statistics, calculate column densities, and compare abundances across various stages of low-mass star formation. Our findings have more than doubled COM detection statistics in cold cores and show COMs are prevalent in the gas before star and planet formation in the Perseus molecular cloud. 

Abstract The Milky Way is a barred spiral galaxy withbar lanesthat bring gas toward the Galactic center. Gas flowing along these bar lanes often overshoots, and instead of accreting onto the Central Molecular Zone (CMZ), it collides with the bar lane on the opposite side of the Galaxy. We observed G5, a cloud that we believe is the site of one such collision, near the Galactic center at (ℓ,b) = ( +5.4, −0.4) with the Atacama Large Millimeter/submillimeter Array/Atacama Compact Array. We took measurements of the spectral lines¹²COJ= 2 → 1,¹³COJ= 2 → 1, C¹⁸OJ= 2 → 1, H₂COJ= 3₀₃→ 2₀₂, H₂COJ= 3₂₂→ 2₂₁, CH₃OHJ= 4₂₂→ 3₁₂, OCSJ= 18 → 17, and SiOJ= 5 → 4. We observed a velocity bridge between two clouds at ∼50 and ∼150 km s⁻¹in our position–velocity diagram, which is direct evidence of a cloud–cloud collision. We measured an average gas temperature of ∼60 K in G5 using H₂CO integrated-intensity line ratios. We observed that the¹²C/¹³C ratio in G5 is consistent with optically thin, or at most marginally optically thick¹²CO. We measured $1.5\times {10}^{19}{\mathrm{cm}}^{-2}{\left(\mathrm{K}\mathrm{km}{\mathrm{s}}^{-1}\right)}^{-1}$for the local X_CO, 10–20× less than the average Galactic value. G5 is strong direct observational evidence of gas overshooting the CMZ and colliding with a bar lane on the opposite side of the Galactic center. 

ABSTRACT Low-mass stars like our Sun begin their evolution within cold (10 K) and dense (∼105 cm−3) cores of gas and dust. The physical structure of starless cores is best probed by thermal emission of dust grains. We present a high-resolution dust continuum study of the starless cores in the B10 region of the Taurus Molecular Cloud. New observations at 1.2 and 2.0 mm (12 and 18 arcsec resolution) with the NIKA2 instrument on the IRAM 30m have probed the inner regions of 14 low-mass starless cores. We perform sophisticated 3D radiative transfer modelling for each of these cores through the radiative transfer framework pandora, which utilizes RADMC-3D. Model best-fits constrain each cores’ central density, density slope, aspect ratio, opacity, and interstellar radiation field strength. These ‘typical’ cores in B10 span central densities from 5 × 104 to 1 × 106 cm−3, with a mean value of 2.6 × 105 cm−3. We find the dust opacity laws assumed in the 3D modelling, as well as the estimates from Herschel, have dust emissivity indices, β’s, on the lower end of the distribution constrained directly from the NIKA2 maps, which averages to β = 2.01 ± 0.48. From our 3D density structures and archival NH3 data, we perform a self-consistent virial analysis to assess each core’s stability. Ignoring magnetic field contributions, we find nine out of the 14 cores (64  per cent) are either in virial equilibrium or are bound by gravity and external pressure. To push the bounded cores back to equilibrium, an effective magnetic field difference of only ∼15 $$\mu$$G is needed. 

ABSTRACT Understanding the chemical processes during starless core and prestellar core evolution is an important step in understanding the initial stages of star and disc formation. This project is a study of deuterated ammonia, o-NH2D, in the L1251 star-forming region towards Cepheus. Twenty-two dense cores (20 of which are starless or prestellar, and two of which have a protostar), previously identified by p-NH3 (1,1) observations, were targeted with the 12m Arizona Radio Observatory telescope on Kitt Peak. o-NH2D J$$_{\rm {K_a} \rm {K_c}}^{\pm } =$$1_{11}^{+} \rightarrow 1_{01}^{-}$$ was detected in 13 (59 per cent) of the NH3-detected cores with a median sensitivity of $$\sigma _{T_{mb}} = 17$$ mK. All cores detected in o-NH2D at this sensitivity have p-NH3 column densities >1014 cm−2. The o-NH2D column densities were calculated using the constant excitation temperature (CTEX) approximation while correcting for the filling fraction of the NH3 source size. The median deuterium fraction was found to be 0.11 (including 3σ upper limits). However, there are no strong, discernible trends in plots of deuterium fraction with any physical or evolutionary variables. If the cores in L1251 have similar initial chemical conditions, then this result is evidence of the cores physically evolving at different rates. 

ABSTRACT Determining the level of chemical complexity within dense starless and gravitationally bound pre-stellar cores is crucial for constructing chemical models, which subsequently constrain the initial chemical conditions of star formation. We have searched for complex organic molecules (COMs) in the young starless core L1521E, and report the first clear detection of dimethyl ether (CH3OCH3), methyl formate (HCOOCH3), and vinyl cyanide (CH2CHCN). Eight transitions of acetaldehyde (CH3CHO) were also detected, five of which (A states) were used to determine an excitation temperature to then calculate column densities for the other oxygen-bearing COMs. If source size was not taken into account (i.e. if filling fraction was assumed to be one), column density was underestimated, and thus we stress the need for higher resolution mapping data. We calculated L1521E COM abundances and compared them to other stages of low-mass star formation, also finding similarities to other starless/pre-stellar cores, suggesting related chemical evolution. The scenario that assumes formation of COMs in gas-phase reactions between precursors formed on grains and then ejected to the cold gas via reactive desorption was tested and was unable to reproduce observed COM abundances, with the exception of CH3CHO. These results suggest that COMs observed in cold gas are formed not by gas-phase reactions alone, but also through surface reactions on interstellar grains. Our observations present a new, unique challenge for existing theoretical astrochemical models. 

Abstract The molecular gas in galaxies traces both the fuel for star formation and the processes that can enhance or suppress star formation. Observations of the molecular gas state can thus point to when and why galaxies stop forming stars. In this study, we present Atacama Large Millimeter/submillimeter Array observations of the molecular gas in galaxies evolving through the post-starburst phase. These galaxies have low current star formation rates (SFRs), regardless of the SFR tracer used, with recent starbursts ending within the last 600 Myr. We present CO (3–2) observations for three post-starburst galaxies, and dense gas HCN/HCO⁺/HNC (1–0) observations for six (four new) post-starburst galaxies. The post-starbursts have low excitation traced by the CO spectral-line energy distribution up to CO (3–2), more similar to early-type than starburst galaxies. The low excitation indicates that lower density rather than high temperatures may suppress star formation during the post-starburst phase. One galaxy displays a blueshifted outflow traced by CO (3–2). MaNGA observations show that the ionized gas velocity is disturbed relative to the stellar velocity field, with a blueshifted component aligned with the molecular gas outflow, suggestive of a multiphase outflow. Low ratios of HCO⁺/CO, indicating low fractions of dense molecular gas relative to the total molecular gas, are seen throughout post-starburst phase, except for the youngest post-starburst galaxy considered here. These observations indicate that the impact of any feedback or quenching processes may be limited to low excitation and weak outflows in the cold molecular gas during the post-starburst phase. 

ABSTRACT Filamentary structures have been found nearly ubiquitously in molecular clouds and yet their formation and evolution is still poorly understood. We examine a segment of Taurus Molecular Cloud 1 (TMC-1) that appears as a single, narrow filament in continuum emission from dust. We use the Regularized Optimization for Hyper-Spectral Analysis (ROHSA), a Gaussian decomposition algorithm that enforces spatial coherence when fitting multiple velocity components simultaneously over a data cube. We analyse HC5N (9–8) line emission as part of the Green Bank Ammonia Survey and identify three velocity-coherent components with ROHSA. The two brightest components extend the length of the filament, while the third component is fainter and clumpier. The brightest component has a prominent transverse velocity gradient of 2.7 ± 0.1 km s−1 pc−1 that we show to be indicative of gravitationally induced inflow. In the second component, we identify regularly spaced emission peaks along its length. We show that the local minima between pairs of adjacent HC5N peaks line up closely with submillimetre continuum emission peaks, which we argue is evidence for fragmentation along the spine of TMC-1. While coherent velocity components have been described as separate physical structures in other star-forming filaments, we argue that the two bright components identified in HC5N emission in TMC-1 are tracing two layers in one filament: a lower density outer layer whose material is flowing under gravity towards the higher density inner layer of the filament.